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Composition-Driven Carbon Dioxide Flooding
1982 - 1988
During the 1982–1988 period, crude oil composition strongly influenced the minimum miscibility pressure and miscible-type displacement thresholds for carbon dioxide floods, with oil molecular size and extractability shaping CO2/oil interactions. Core floods and simulations showed that multicontact CO2/crude phase behavior couples with bypassing and viscous fingering, reducing sweep efficiency relative to stable displacements; near-front mobile-water saturations further influence residual oil and encourage mobility-control approaches in certain reservoirs. Gravity-stable processes and slug- or WAG-like strategies addressed density contrasts to improve heavy-oil recovery, with early field pilots demonstrating practical feasibility. Influential Works: A key early finding demonstrated that crude oil composition strongly governs the minimum miscibility pressure for carbon dioxide floods, reshaping oil screening and flood design. Follow-up work quantified impurity effects on minimum miscibility pressures and enrichment levels for CO2 and rich-gas displacements, establishing impurity considerations and multicontact flood strategies. A broader synthesis outlined the promise and constraints of carbon dioxide flooding, guiding subsequent modeling and field tests.
• Oil composition strongly influences the minimum miscibility pressure (MMP) and miscible-type displacement thresholds in CO2 floods; data suggest hydrocarbon molecular size and extractability govern CO2/oil interactions, challenging earlier reports of negligible oil-composition effects [1], [10], [6].
• Phase-behavior interactions with macroscopic bypassing constrain ultimate oil recovery in CO2 floods; core floods and simulations reveal that multicontact CO2/crude phase behavior couples with bypassing and viscous fingering to reduce sweep efficiency compared with stable displacements [3], [9], [19].
• Mobile-water effects near the displacement front alter CO2 flood performance; AGWIP and related experiments show mobile-water saturations influence residual oil saturation and that foam/mobility-control approaches can improve sweep in certain reservoirs [2], [20], [5].
• Gravity-stable miscible CO2 processes address density contrasts and slug design to maintain favorable gravity segregation, enabling improved heavy-oil recovery; laboratory designs and field demonstrations illustrate practical implementation in carbonate and sandstone reservoirs [15], [17], [16].
• Field-scale CO2 miscible flooding pilots demonstrate practical feasibility across diverse reservoirs, testing slug strategies, WAG-like sequences, and interaction with local geology; lessons come from multiple field studies and pilots [11], [13], [4], [16].
Foam-Enhanced Carbon Dioxide Flooding
1989 - 1996
Conformance-Driven CO2 Flooding
1997 - 2003
Multiphase CO2 Flooding Dynamics
2004 - 2010
Integrated CO2-EOR Framework
2011 - 2017
Smart Mobility-Controlled ScCO2 Flooding
2018 - 2024